The history of water salinity in the Pearl River estuary,China, during the Late Quaternary

This research reconstructed the Late Quaternary salinity history of the Pearl River estuary, China, from diatom records of four sedimentary cores. The reconstruction was produced through the application of a diatom–salinity transfer function developed based on 77 modern surface sediment samples collected across the estuary from shallow marine environment to deltaic distributaries. The statistical analysis indicates that the majority of sediment samples from the cores has good modern analogues, thus the reconstructions are reliable. The reconstructed salinity history shows the older estuarine sequence formed during the last interglacial was deposited under similar salinity conditions to the younger estuarine sequence, which was formed during the present interglacial. Further analysis into the younger estuarine sequence reveals the interplays between sea level, monsoon‐driven freshwater discharge, and deltaic shoreline movement, key factors that have influenced water salinity in the estuary. In particular, a core from the delta plain shows the effects of sea‐level change and deltaic progradation, while cores from the mouth region of the estuary reveal changes of monsoon‐driven freshwater discharge. This study demonstrates the advantages of quantitative salinity reconstructions to improve the quality of reconstruction and allow direct comparison with other quantitative records and the instrumentally observed values of salinity. Copyright © 2010 John Wiley & Sons, Ltd.     

Successional changes in soil and hyporheic nitrogen fertility on an alluvial flood plain: implications for riparian vegetation

In floodplain primary succession, vegetation colonizes nitrogen-poor alluvial deposits and fertility improves as soil nitrogen accumulates over time. It is generally assumed that vegetation assimilates the vast majority of its nitrogen from the soil; however, recent studies have suggested that the hyporheic zone also may be an important nitrogen source. We investigated the potential relative importance of hyporheic nitrogen by comparing fertility indices, specifically total (TN), dissolved inorganic (DIN), potentially mineralizable (PMN) and ion exchange resin nitrogen (IERN) in both soils and the hyporheic zone at early, mid and late succession stands on an expansive river flood plain. We also constructed mesocosms to assess growth of cottonwood cuttings with access to soil and/or hyporheic water. We found TN and PMN increased from early to mid succession in both the soil (to 10 cm) and hyporheic zone (in a 10 cm layer). While TN, DIN and PMN were an order of magnitude higher in the soil than in the hyporheic zone, IERN was higher in the hyporheic zone, indicating that subsurface flow through the flood plain may be important in delivering nitrogen to the root zone. However, even when flux was added to the hyporheic PMN pool, nitrogen availability in the hyporheic zone (in a 10 cm layer) was vastly lower than soil PMN (to 10 cm). Further, the instantaneous standing stock of DIN in the surface soil alone was about equal to the sum of the DIN pool, the mean subsurface flux and the PMN pool in a 10 cm layer of hyporheic zone. In the mesocosm experiment, cottonwood cuttings with access to both soil and hyporheic water grew fastest; however, they also had the lowest foliar nitrogen concentrations, indicating that this was not due to greater nitrogen availability. In the field, nitrogen content of cottonwood foliage increased along with soil (but potentially hyporheic as well) nitrogen accumulation during succession, suggesting the vegetation responded to increasing nitrogen fertility. We conclude that at least on a per unit-volume basis, the hyporheic zone probably provides little nitrogen relative to the surface soil, except on new alluvial bars that characteristically are nitrogen poor. Therefore, the hyporheic zone is probably a much smaller nitrogen source for mature forests relative to the surface soil unless the vegetation exploits a much larger volume of the hyporheic zone than surface soil.     

The roles of surface heat flux and ocean heat transport convergence in determining Atlantic Ocean temperature variability

The temperature variability of the Atlantic Ocean is investigated using an eddy-permitting (1/4°) global ocean model (ORCA-025) forced with historical surface meteorological fields from 1958 to 2001. The simulation of volume-averaged temperature and the vertical structure of the zonally averaged temperature trends are compared with those from observations. In regions with a high number of observations, in particular above a depth of 500 m and between 22° N and 65° N, the model simulation and the dataset are in good agreement. The relative contribution of variability in ocean heat transport (OHT) convergence and net surface heat flux to changes in ocean heat content is investigated with a focus on three regions: the subpolar and subtropical gyres and the tropics. The surface heat flux plays a relatively minor role in year-to-year changes in the subpolar and subtropical regions, but in the tropical North Atlantic, its role is of similar significance to the ocean heat transport convergence. The strongest signal during the study period is a cooling of the subpolar gyre between 1970 and 1990, which subsequently reversed as the mid-latitude OHT convergence transitioned from an anomalously weak to an anomalously strong state. We also explore whether model OHT anomalies can be linked to surface flux anomalies through a Hovmöller analysis of the Atlantic sector. At low latitudes, increased ocean heat gain coincides with anomalously strong northward transport, whereas at mid-high latitudes, reduced ocean heat loss is associated with anomalously weak heat transport.     

It starts at home? Climate policies targeting household consumption and behavioral decisions are key to low-carbon futures

Through their consumption behavior, households are responsible for 72% of global greenhouse gas emissions. Thus, they are key actors in reaching the 1.5 °C goal under the Paris Agreement. However, the possible contribution and position of households in climate policies is neither well understood, nor do households receive sufficiently high priority in current climate policy strategies. This paper investigates how behavioral change can achieve a substantial reduction in greenhouse gas emissions in European high-income countries. It uses theoretical thinking and some core results from the HOPE research project, which investigated household preferences for reducing emissions in four European cities in France, Germany, Norway and Sweden. The paper makes five major points: First, car and plane mobility, meat and dairy consumption, as well as heating are the most dominant components of household footprints. Second, household living situations (demographics, size of home) greatly influence the household potential to reduce their footprint, even more than country or city location. Third, household decisions can be sequential and temporally dynamic, shifting through different phases such as childhood, adulthood, and illness. Fourth, short term voluntary efforts will not be sufficient by themselves to reach the drastic reductions needed to achieve the 1.5 °C goal; instead, households need a regulatory framework supporting their behavioral changes. Fifth, there is a mismatch between the roles and responsibilities conveyed by current climate policies and household perceptions of responsibility. We then conclude with further recommendations for research and policy.     

Multidimensional upstream weighting for multiphase transport on general grids

The governing equations for multiphase flow in porous media have a mixed character, with both nearly elliptic and nearly hyperbolic variables. The flux for each phase can be decomposed into two parts: (1) a geometry- and rock-dependent term that resembles a single-phase flux; and (2) a mobility term representing fluid properties and rock–fluid interactions. The first term is commonly discretized by two- or multipoint flux approximations (TPFA and MPFA, respectively). The mobility is usually treated with single-point upstream weighting (SPU), also known as dimensional or donor cell upstream weighting. It is well known that when simulating processes with adverse mobility ratios, SPU suffers from grid orientation effects. An important example of this, which will be considered in this work, is the displacement of a heavy oil by water. For these adverse mobility ratio flows, the governing equations are unstable at the modeling scale, rendering a challenging numerical problem. These challenges must be addressed in order to avoid systematic biasing of simulation results. In this work, we present a framework for multidimensional upstream weighting for multiphase flow with buoyancy on general two-dimensional grids. The methodology is based on a dual grid, and the resulting transport methods are provably monotone. The multidimensional transport methods are coupled with MPFA methods to solve the pressure equation. Both explicit and fully implicit approaches are considered for time integration of the transport equations. The results show considerable reduction of grid orientation effects compared to SPU, and the explicit multidimensional approach allows larger time steps. For the implicit method, the total number of non-linear iterations is also reduced when multidimensional upstream weighting is used.     

Implications of recent sea level rise science for low-elevation areas in coastal cities of the conterminous U.S.A.

Recently published work estimates that global sea level rise (SLR) approaching or exceeding 1 m by 2100 is plausible, thus significantly updating projections by the Fourth Assessment of the Intergovernmental Panel on Climate Change. Furthermore, global greenhouse gas (GHG) emissions over the 21st century will not only influence SLR in the next ??90 years, but will also commit Earth to several meters of additional SLR over subsequent centuries. In this context of worsening prospects for substantial SLR, we apply a new geospatial dataset to calculate low-elevation areas in coastal cities of the conterminous U.S.A. potentially impacted by SLR in this and following centuries. In total, 20 municipalities with populations greater than 300,000 and 160 municipalities with populations between 50,000 and 300,000 have land area with elevations at or below 6 m and connectivity to the sea, as based on the 1 arc-second National Elevation Dataset. On average, approximately 9% of the area in these coastal municipalities lies at or below 1 m. This figure rises to 36% when considering area at or below 6 m. Areal percentages of municipalities with elevations at or below 1?C6 m are greater than the national average along the Gulf and southern Atlantic coasts. In contrast to the national and international dimensions of and associated efforts to curb GHG emissions, our comparison of low-elevation areas in coastal cities of the conterminous U.S.A. clearly shows that SLR will potentially have very local, and disproportionate, impacts.     

Thermal history and origin of the Tanzanian Craton from Pb isotope thermochronology of feldspars from lower crustal xenoliths

Common and radiogenic Pb isotopic compositions of plagioclase and anti-perthitic feldspars from granulite-facies lower crustal xenoliths from the Labait Volcano on the eastern margin of the Tanzanian Craton have been measured via laser ablation MC-ICP-MS. Common Pb in plagioclase and a single stage Pb evolution model indicate that the lower crust of the Tanzanian Craton was extracted from mantle having a ²³⁸U/²⁰⁴Pb of 8.1 ± 0.3 and a ²³²Th/²³⁸U of 4.3 ± 0.1 at 2.71 ± 0.09 Ga (all uncertainties are 2σ). Since 2.4 Ga, some orthoclase domains within anti-perthites have evolved with a maximum ²³⁸U/²⁰⁴Pb of 6 and ²³²Th/²³⁸U of 4.3. The spread in Pb isotopic composition in the anti-perthitic feldspars yields single crystal Pb–Pb isochrons of ～ 2.4 Ga, within uncertainty of U–Pb zircon ages from the same sample suite. The Pb isotopic heterogeneities imply that these granulites resided at temperatures < 600 °C in the lower crust of the Tanzanian Craton from ca. 2.4 Ga to the present. In concert with the chemistry of surface samples, mantle xenoliths, and lower crustal xenoliths, our data imply that the cratonic lithosphere in Tanzania formed ca. ～ 2.7 Ga, in a convergent margin setting, and has remained undisturbed since 2.7 Ga.     

Thermodynamic characterization of boltwoodite and uranophane: Enthalpy of formation and aqueous solubility

Boltwoodite and uranophane are uranyl silicates common in oxidized zones of uranium ore deposits. An understanding of processes that impact uranium transport in the environment, especially pertaining to the distribution of uranium between solid phases and aqueous solutions, ultimately requires determination of thermodynamic parameters for such crystalline materials. We measured formation enthalpies of synthetic boltwoodites, K(UO₂)(HSiO₄)·H₂O and Na(UO₂)(HSiO₄)·H₂O, and uranophane, Ca(UO₂)₂(HSiO₄)₂·5H₂O, by high temperature oxide melt solution calorimetry. We also studied the aqueous solubility of these phases from both saturated and undersaturated conditions at a variety of pH. The combined data permit the determination of standard enthalpies, entropies and Gibbs free energies of formation for each phase and analysis of its potential geological impact from a thermodynamic point of view.     

The domestic divide: Access to the Internet in New Zealand

We use unit records of the 2006 census to show that access to the Internet in the home varies geographically in New Zealand primarily as a result of demographic and socio‐economic differences among individuals. Of particular significance is the much lower rates of domestic access experienced by Māori and Pacific Island individuals even after controlling for differences in their age, gender, education, income, occupation and settlement type. While differences in Internet access by ethnicity has been noted before, it is the magnitude and persistence of this difference in New Zealand after controlling for correlated factors that renders this study unique. Our results have important implications in an education environment increasingly reliant on Web access, but they also raise questions about the extent of access to the Internet outside the home.     

An empirical model of subcritical bedform migration

The ability to predict bedform migration in rivers is critical for estimating bed material load, yet there is no relation for predicting bedform migration (downstream translation) that covers the full range of conditions under which subcritical bedforms develop. Here, the relation between bedform migration rates and transport stage is explored using a field and several flume data sets. Transport stage is defined as the non‐dimensional Shields stress divided by its value at the threshold for sediment entrainment. Statistically significant positive correlations between both ripple and dune migration rates and transport stage are found. Stratification of the data by the flow depth to grain‐size ratio improved the amount of variability in migration rates that was explained by transport stage to ca 70%. As transport stage increases for a given depth to grain‐size ratio, migration rates increase. For a given transport stage, the migration rate increases as the flow depth to grain‐size ratio gets smaller. In coarser sediment, bedforms move faster than in finer sediment at the same transport stage. Normalization of dune migration rates by the settling velocity of bed sediment partially collapses the data. Given the large amount of variability that arises from combining data sets from different sources, using different equipment, the partial collapse is remarkable and warrants further testing in the laboratory and field.